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Additional info for 5th FORUM ON NEW MATERIALS PART C Proceedings of the 5th Forum on New Materials, part of CIMTEC 2010-12 th International Ceramics Congress and 5th Forum on New Materials Montecatini Terme, Italy, June 13-18, 2010

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58 1200 (1980) [8] G. S. Painter ; Phys. Rev. B 24 4264(1981) [9] O. K. Anderson Phys. Rev. B 12 3060(1975) [10] T. Takeda and J. Kubler ; J. Phys F9 661(1979) [11] See, for example D. M. Rowe; CRC Handbook of Thermoelectrics (CRC Press, New York, 1995). C. M. G. Pinsker ;“Electron diffraction study of the semiconducting compoubd AgTe2Tl”, Soviet Physics-Crystallography, translated from Kristallografiya 9(5),626 (1965). O. S. M. G. Pinsker, “Crystal Structure of Physics-Crystallography, translated from Kristallografiya 17(2),237 (1965).

The unit cell contains two smaller 20-atom cages and six larger 24-atom cages. In Ba8Ga16Si30, the framework consists of Ga and Si atoms. Two Ba atoms are located at the crystallographic Fig. 1. Structure of 20-atom and positions 2a site in the smaller 20-atom cages and six Ba 24-atom cages and guest atoms atoms are located at the 6d site in the larger 24-atom cages. The low glass-like thermal conductivity is attributed to the in type-I clathrate. guest-host interactions whereby the localized vibrations “rattling” of guest atoms inside the cages interact strongly with the acoustic modes of framework (host).

1Al show almost the same S and ρ. The calculated PF is presented in Fig. 5. PF was enhanced by the additional Ti-substitution resulting from the enhancement of electrical conductivity and S. 03 at 395 K. 1Al. 0 300 400 500 600 700 800 Temperature (K) Fig. 1Al sintered alloy. 0 300 400 500 600 700 800 Temperature (K) Fig. 1Al sintered alloy. As shown in Fig. 1Al. Therefore, the κ reduction effect is attributable to the large difference in atomic mass between Sb and the constituent elements of Fe2VAl alloy.

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5th FORUM ON NEW MATERIALS PART C Proceedings of the 5th Forum on New Materials, part of CIMTEC 2010-12 th International Ceramics Congress and 5th Forum on New Materials Montecatini Terme, Italy, June 13-18, 2010 by Edited by Pietro VINCENZINI World Academy of Ceramics and National Research Council, Italy Co-edited by Kunihito KOUMOTO, Nagoya University, Japan Nicola ROMEO, University of Parma,


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